Oxidación anódica de NADH sobre electrodos de carbón vítreo modificados con películas de surfactantes-hidrotalcita- ácido ferrocenodicarboxílico

Isis Ledezma; Lenys Fernández

Oxidación anódica de NADH sobre electrodos de carbón vítreo modificados con películas de surfactantes-hidrotalcita- ácido ferrocenodicarboxílico

^*Autor correspondiente de este trabajo

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Resumen

We report on the electrochemical behavior of chemically modified glassy carbon (GC) electrodes by using surfactant/hydrotalcite (HT) films, incorporating ferrocenedicarboxylic acid (FDC) as redox mediators for NADH. The FDC retained in the films displayed two welldefined voltammetric peaks. They correspond to the redox process ferrocene/ferrocenium. The type of surfactants adsorbed have a pronounced effect on the FDC adsorption on the HT. The modified electrodes are found to give stable and reproducible electrocatalytic response to NADH and axhibit good stability.

Título traducido de la contribución	Anodic oxidation of NADH at surfactant-hydrotalciteferrocenedicarboxylic acid glassy carbon modified electrodes
Idioma original	Español
Publicación	Revista Tecnica de la Facultad de Ingenieria Universidad del Zulia
Volumen	30
N.º	SPEC. ISSUE
Estado	Publicada - nov. 2007
Publicado de forma externa	Sí

Palabras clave

Clay-modified electrode
Nicotinamide adenine-dinucleotide oxidation
Synthetic hydrotalcite-like clay

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title = "Oxidaci{\'o}n an{\'o}dica de NADH sobre electrodos de carb{\'o}n v{\'i}treo modificados con pel{\'i}culas de surfactantes-hidrotalcita- {\'a}cido ferrocenodicarbox{\'i}lico",

abstract = "We report on the electrochemical behavior of chemically modified glassy carbon (GC) electrodes by using surfactant/hydrotalcite (HT) films, incorporating ferrocenedicarboxylic acid (FDC) as redox mediators for NADH. The FDC retained in the films displayed two welldefined voltammetric peaks. They correspond to the redox process ferrocene/ferrocenium. The type of surfactants adsorbed have a pronounced effect on the FDC adsorption on the HT. The modified electrodes are found to give stable and reproducible electrocatalytic response to NADH and axhibit good stability.",

keywords = "Clay-modified electrode, Nicotinamide adenine-dinucleotide oxidation, Synthetic hydrotalcite-like clay",

author = "Isis Ledezma and Lenys Fern{\'a}ndez",

year = "2007",

month = nov,

language = "Espa{\~n}ol",

volume = "30",

journal = "Revista Tecnica de la Facultad de Ingenieria Universidad del Zulia",

issn = "0254-0770",

publisher = "Revista Tecnica de la Facultad de Ingeniera",

number = "SPEC. ISSUE",

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TY - JOUR

T1 - Oxidación anódica de NADH sobre electrodos de carbón vítreo modificados con películas de surfactantes-hidrotalcita- ácido ferrocenodicarboxílico

AU - Ledezma, Isis

AU - Fernández, Lenys

PY - 2007/11

Y1 - 2007/11

N2 - We report on the electrochemical behavior of chemically modified glassy carbon (GC) electrodes by using surfactant/hydrotalcite (HT) films, incorporating ferrocenedicarboxylic acid (FDC) as redox mediators for NADH. The FDC retained in the films displayed two welldefined voltammetric peaks. They correspond to the redox process ferrocene/ferrocenium. The type of surfactants adsorbed have a pronounced effect on the FDC adsorption on the HT. The modified electrodes are found to give stable and reproducible electrocatalytic response to NADH and axhibit good stability.

AB - We report on the electrochemical behavior of chemically modified glassy carbon (GC) electrodes by using surfactant/hydrotalcite (HT) films, incorporating ferrocenedicarboxylic acid (FDC) as redox mediators for NADH. The FDC retained in the films displayed two welldefined voltammetric peaks. They correspond to the redox process ferrocene/ferrocenium. The type of surfactants adsorbed have a pronounced effect on the FDC adsorption on the HT. The modified electrodes are found to give stable and reproducible electrocatalytic response to NADH and axhibit good stability.

KW - Clay-modified electrode

KW - Nicotinamide adenine-dinucleotide oxidation

KW - Synthetic hydrotalcite-like clay

UR - https://www.scopus.com/pages/publications/80052571624

M3 - Artículo

AN - SCOPUS:80052571624

SN - 0254-0770

VL - 30

JO - Revista Tecnica de la Facultad de Ingenieria Universidad del Zulia

JF - Revista Tecnica de la Facultad de Ingenieria Universidad del Zulia

IS - SPEC. ISSUE

ER -

Oxidación anódica de NADH sobre electrodos de carbón vítreo modificados con películas de surfactantes-hidrotalcita- ácido ferrocenodicarboxílico

Resumen

Palabras clave

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