TY - JOUR
T1 - Effect of graphene oxide dosage on the thermal and rheological behavior of asphalt for tropical road conditions
AU - Mendoza, Erick
AU - Tene, Talia
AU - Albuja-Sánchez, Jorge
AU - Cuenca, Guisella
AU - Ramón, John
AU - Anzules, David
AU - Vacacela Gomez, Cristian
AU - Cruz Salazar, Yolenny
AU - Caputi, Lorenzo S.
AU - Straface, Salvatore
N1 - Publisher Copyright:
Copyright © 2025 Mendoza, Tene, Albuja-Sánchez, Cuenca, Ramón, Anzules, Vacacela Gomez, Cruz Salazar, Caputi and Straface.
PY - 2025
Y1 - 2025
N2 - This study investigates graphene oxide (GO) as a low-percent modifier for AC-30 asphalt used in tropical conditions. GO was added at 0.2, 0.4, and 0.6 wt% and tested through standard binder tests and RTFO short-term aging. Unaged binders with GO showed increased viscosity and hardness—viscosity rose by up to approximately 26%, penetration decreased by about 8%–13%, and the softening point rose slightly—indicating a stiffer initial matrix. During mixing at 135 °C–165 °C, both rotational and kinematic viscosities increased, with the highest gains near 0.4 wt%, suggesting a non-linear response to dosage. Under RTFO aging, GO-modified binders exhibited a higher viscosity aging index than the unmodified AC-30, indicating that GO enhances initial stiffness and does not compromise short-term oxidative hardening. Flash and fire points did not show systematic reductions at these dosages. Overall, sub-percent GO improves high-temperature rheology relevant for hot-climate pavements, but there is a trade-off between better early rutting resistance and potential stiffening with aging. Future research will include PAV/DSR testing and analysis of dispersion better to understand long-term behavior and processing at the plant level.
AB - This study investigates graphene oxide (GO) as a low-percent modifier for AC-30 asphalt used in tropical conditions. GO was added at 0.2, 0.4, and 0.6 wt% and tested through standard binder tests and RTFO short-term aging. Unaged binders with GO showed increased viscosity and hardness—viscosity rose by up to approximately 26%, penetration decreased by about 8%–13%, and the softening point rose slightly—indicating a stiffer initial matrix. During mixing at 135 °C–165 °C, both rotational and kinematic viscosities increased, with the highest gains near 0.4 wt%, suggesting a non-linear response to dosage. Under RTFO aging, GO-modified binders exhibited a higher viscosity aging index than the unmodified AC-30, indicating that GO enhances initial stiffness and does not compromise short-term oxidative hardening. Flash and fire points did not show systematic reductions at these dosages. Overall, sub-percent GO improves high-temperature rheology relevant for hot-climate pavements, but there is a trade-off between better early rutting resistance and potential stiffening with aging. Future research will include PAV/DSR testing and analysis of dispersion better to understand long-term behavior and processing at the plant level.
KW - asphalt
KW - graphene oxide
KW - hardness
KW - resistance
KW - viscosity
UR - https://www.scopus.com/pages/publications/105020740621
U2 - 10.3389/fchem.2025.1691517
DO - 10.3389/fchem.2025.1691517
M3 - Article
AN - SCOPUS:105020740621
SN - 2296-2646
VL - 13
JO - Frontiers in Chemistry
JF - Frontiers in Chemistry
M1 - 1691517
ER -