Characterization of surfactant/hydrotalcite-like clay/glassy carbon modified electrodes: Oxidation of phenol

María Hernández, Lenys Fernández, Carlos Borrás, Jorge Mostany, Hermes Carrero

Producción científica: Contribución a una revistaArtículorevisión exhaustiva

39 Citas (Scopus)

Resumen

The characteristics of hydrotalcite (HT)-like clay films containing ionic and nonionic surfactants and their ability to oxidize phenol have been examined. The HT clay (Co/Al-NO3) was synthesized by coprecipitation techniques and then modified with surfactants such as sodium dodecylbenzenesulfonate (SDBS), octylphenoxypolyethoxyethanol (TX100) or cetylpyridinium bromide (CPB). X-ray diffraction analysis revealed that the interlayer basal spacing varied depending on the type of surfactant retained by the HT. The presence of SDBS and CPB expanded the HT interlayer, which in the presence of TX100 did not show an appreciable change. Phenol oxidation is favored at surfactant-HT-GC modified electrodes, after a preconcentration time, compared to phenol oxidation at HT-GC or GC electrodes. Surfactant-HT-GC modified electrodes display good stability in continuous electrochemical phenol oxidation. At pH values between 6 and 10.8, both SDBS-HT-GC and TX100-HT-GC modified electrodes seem to be promising electrodes for the detection of phenol in water; while the CPB-HT-GC modified electrode should be affected by the inorganic anions.

Idioma originalInglés
Páginas (desde-hasta)245-256
Número de páginas12
PublicaciónAnalytica Chimica Acta
Volumen597
N.º2
DOI
EstadoPublicada - 10 ago. 2007
Publicado de forma externa

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