Photocatalytic activity of metalloporphyrin-Titanium mixtures in microemulsions

Lorean Madriz, Hermes Carrero, Julio Herrera, Aivlé Cabrera, Nieves Canudas, Lenys Fernández

Research output: Contribution to journalArticlepeer-review

13 Scopus citations

Abstract

This report explores the photocatalytic activity of TiO2, Ti(IV) citrate and Zn(II) tetraphenyl porphyrin (ZnTPP) and its mixtures in water/oil (W/O) and O/W microemulsion (μE). The 4-chlorophenol was used to assess the efficiency of the photoactive compounds in a degradation process. A simple photoelectrochemical study based on cyclic voltammetry was also developed. The results revealed that most of the photocatalytic procedures developed are effective in the degradation process. However, phenol was the major product obtained.

Original languageEnglish
Pages (from-to)236-243
Number of pages8
JournalTopics in Catalysis
Volume54
Issue number1-4
DOIs
StatePublished - Mar 2011
Externally publishedYes

Keywords

  • Microemulsion
  • Photocatalysis
  • Porphyrin
  • Titanium dioxide
  • Titanium(IV) citrate

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